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Evolution of structure and properties of multi-component (AlCrTaTiZr)Ox films
Journal article   Peer reviewed

Evolution of structure and properties of multi-component (AlCrTaTiZr)Ox films

Miao-I. Lin, Ming-Hung Tsai, Wan-Jui Shen and Jien-Wei Yeh
Thin Solid Films, Vol.518(10), pp.2732-2737
01/03/2010

Abstract

Amorphous structure Hard coating High-entropy alloy Multi-component oxide Reactive sputtering
(AlCrTaTiZr)O x films were deposited at 350 °C by DC magnetron sputtering from high-entropy alloy target. Oxygen concentration increases with oxygen flow ratio, and saturates near 67 at.%. As-deposited films have an amorphous structure. Their hardness fall in the range of 8-13 GPa. All amorphous oxide films maintain their amorphous structure up to 800 °C for at least 1 h. After 900 °C 5 h annealing, crystalline phases with the structures of ZrO 2 , TiO 2 , or Ti 2 ZrO 6 form. Annealing enhances mechanical properties of the films. Their hardness and modulus attain to the values about 20 and 260 GPa, respectively. The resistivity of the metallic films is around 10 2 μΩ cm but drastically rises to 10 12 μΩ cm when oxygen concentration increases. © 2009 Elsevier B.V. All rights reserved.

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