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Femtosecond probing of photodissociation dynamics in acyl cyanides
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Femtosecond probing of photodissociation dynamics in acyl cyanides

I.R. Lee, Yu-Chieh Chung, Wei-Kan Chen, Xiu-Ping HongPo-Yuan Cheng
Journal of Chemical Physics, 卷.115(23), 頁碼.10656-10670
12/2001

摘要

Physics and Astronomy (all) Physical and Theoretical Chemistry
The temporal evolution of the CN(X) products for the photodissociation of two acyl cyanide compounds in the ∼6.4 eV energy region was measured. Data was obtained that provide valuable insights into the photodissociation mechanism of acyl cyanide compounds. It was proposed that the photodissociation occurs via two discernible stages that bring about the two temporal components observed in the product transient growth.

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