Gold-catalyzed cyclization/oxidative [3+2] cycloadditions of 1,5-enynes with nitrosobenzenes without additional oxidants

Chun-Hao Chen; Yen-Ching Tsai; Rai-Shung Liu

doi:10.1002/anie.201209850

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Gold-catalyzed cyclization/oxidative [3+2] cycloadditions of 1,5-enynes with nitrosobenzenes without additional oxidants

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Gold-catalyzed cyclization/oxidative [3+2] cycloadditions of 1,5-enynes with nitrosobenzenes without additional oxidants

Chun-Hao Chen, Yen-Ching Tsai and Rai-Shung Liu

Angewandte Chemie - International Edition, Vol.52(17), pp.4599-4603

22/04/2013

DOI: https://doi.org/10.1002/anie.201209850

Abstract

cycloadditions

enynes

gold

heterocycles

synthetic methods

Golden control: The title reaction (see scheme) proceeds with high stereocontrol to generate the heterocyclic products in good yield. Experiments to probe the mechanism were performed. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Title: Gold-catalyzed cyclization/oxidative [3+2] cycloadditions of 1,5-enynes with nitrosobenzenes without additional oxidants
Creators - without role: Chun-Hao Chen - Department of Chemistry , National Tsing Hua University
Yen-Ching Tsai - Department of Chemistry , National Tsing Hua University
Rai-Shung Liu - Department of Chemistry , National Tsing Hua University
Publication Details: Angewandte Chemie - International Edition, Vol.52(17), pp.4599-4603
Identifiers: 9957777077006774
Academic Unit: Department of Chemistry, College of Science, National Tsing Hua University
Language: English
Resource Type: Journal article

Gold-catalyzed cyclization/oxidative [3+2] cycloadditions of 1,5-enynes with nitrosobenzenes without additional oxidants

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