Gold-catalyzed diastereoselective [2+2+2]-cycloaddition of 1,7-enynes with carbonyl compounds

Deepak B. Huple; Rai-Shung Liu

doi:10.1039/c2cc36219h

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Gold-catalyzed diastereoselective [2+2+2]-cycloaddition of 1,7-enynes with carbonyl compounds

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Peer reviewed

Gold-catalyzed diastereoselective [2+2+2]-cycloaddition of 1,7-enynes with carbonyl compounds

Deepak B. Huple and Rai-Shung Liu

Chemical Communications, Vol.48(89), pp.10975-10977

18/11/2012

DOI: https://doi.org/10.1039/c2cc36219h

Abstract

We report a gold-catalyzed [2+2+2]-cycloaddition of 1,7-enynes with carbonyl species; our experimental data suggest that the resulting oxacyclic cycloadducts arose from an interception of gold-containing cyclobutenium intermediates with carbonyl species. © 2012 The Royal Society of Chemistry.

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Title: Gold-catalyzed diastereoselective [2+2+2]-cycloaddition of 1,7-enynes with carbonyl compounds
Creators - without role: Deepak B. Huple - National Tsing Hua University
Rai-Shung Liu - Department of Chemistry , National Tsing-Hua University
Identifiers: 9957767858106774
Academic Unit: Department of Chemistry, College of Science, National Tsing Hua University
Language: English
Resource Type: Journal article
Publication Details: Chemical Communications, Vol.48(89), pp.10975-10977

Gold-catalyzed diastereoselective [2+2+2]-cycloaddition of 1,7-enynes with carbonyl compounds

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