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Gold-catalyzed reactions of propargylic esters with vinylazides for the synthesis of Z- or E-configured buta-1,3-dien-2-yl esters
Sachin Bhausaheb Wagh
and
Rai-Shung Liu
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Chemical Communications, Vol.51(84), pp.15462-15464
2015
DOI:
https://doi.org/10.1039/c5cc05945c
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Abstract
Gold-catalyzed synthesis of buta-1,3-dien-2-yl esters by the reaction of propargyl esters with vinylazides is described; the reaction mechanism is postulated to involve a vinyl attack of vinylazides at alkenyl gold carbenes.
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Title
Gold-catalyzed reactions of propargylic esters with vinylazides for the synthesis of Z- or E-configured buta-1,3-dien-2-yl esters
Creators - without role
Sachin Bhausaheb Wagh - National Tsing Hua University
Rai-Shung Liu - Department of Chemistry, National Tsing Hua University
Publication Details
Chemical Communications, Vol.51(84), pp.15462-15464
Identifiers
9957771678706774
Copyright
© The Royal Society of Chemistry 2015.
Academic Unit
Department of Chemistry, College of Science, National Tsing Hua University
Language
English
Resource Type
Journal article
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