摘要
A green hydrothermal strategy starting from the Ti powders was developed to synthesis a new kind of well dispersed anatase TiO 2 nanosheets (TNSTs) with dominant (001) facets, successfully avoiding using the HF by choosing the safe substitutes of LiF powder. In contrast to traditional approaches targeting TiO 2 with dominant crystal facets, the strategy presented herein is more convenient, environment friendly and available for industrial production. As a unique structured anode applied in lithium ion battery, the TNSTs could exhibit an extremely high capacity around 215 mAh g -1 at the current density of 100 mA g -1 and preserved capacity over 140 mAh g -1 enduring 200 cycles at 400 mA g -1 . As a further step toward commercialization, a model of lithiating TiO 2 was built for the first time and analyzed by the electrochemical characterizations, and full batteries employing lithiated TNSTs as carbon-free anode versus spinel LiNi x Mn 2-x O 4 (x = 0, 0.5) cathode were configured. The full batteries of TNSTs/LiMn 2 O 4 and TNSTs/LiNi 0.5 Mn 1.5 O 4 have the sustainable advantage of cost-effective and cobalt-free characteristics, and particularly they demonstrated high energy densities of 497 and 580 Wh kg anode -1 (i.e., 276 and 341 Wh kg cathode -1 ) with stable capacity retentions of 95% and 99% respectively over 100 cycles. Besides the intriguing performance in batteries, the versatile synthetic strategy and unique characteristics of TNSTs may promise other attracting applications in the fields of photoreaction, electro-catalyst, electrochemistry, interfacial adsorption photovoltaic devices etc.