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Ground-state properties of nanographite systems with zigzag edges
Journal article   Open access   Peer reviewed

Ground-state properties of nanographite systems with zigzag edges

Toshiya Hikihara, Xiao Hu, Hsiu-Hau Lin and Chung-Yu Mou
Physical Review B - Condensed Matter and Materials Physics, Vol.68(3), pp.354321-354329
07/2003

Abstract

A π-electron network in nanographite systems with zigzag edges exhibits strongly localized edge states, which are expected to have peculiar properties. We study effects of electron-electron interactions on groundstate properties of zigzag nanographite ribbons and open-ended zigzag nanotubes by means of the weak-coupling renormalization group and the density-matrix renormalization-group method. It is shown that the ground state is a spin-singlet Mott insulator with finite charge and spin gaps. We also find that the edge states are robust against the electronic correlations, resulting in edge-effective spins that can flip almost freely. The schematic picture for the low-energy physics of the systems is discussed.
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