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Growth orientation of Cu-Sn IMC in Cu/Sn-3.5Ag/Cu-xZn microbumps and Zn-doped solder joints
Journal article

Growth orientation of Cu-Sn IMC in Cu/Sn-3.5Ag/Cu-xZn microbumps and Zn-doped solder joints

Wei-Yu Chen, Wei Tu, Hsiang-Ching Chang, Tzu-Ting Chou and Jenq-Gong Duh
Materials Letters, Vol.134, pp.184-186
01/11/2014

Abstract

Crystal growth Electron microscopy Intermetallic alloys and compounds Metals and alloys Microstructure
In this study, the evolution of grain structures in Cu/Sn-3.5Ag/Cu-xZn (x=0 or 15 wt%) microbumps and SAC305/Cu-xZn solder joints was investigated. Due to the small size of microbumps, impingement of interface IMCs easily occur. In a Cu/Sn-3.5Ag/Cu (wt%) microbump, the grain orientation of combined intermetallic compounds (IMCs) tends to be homogenous and closely-grouped, allowing cracks to more easily propagate. In order to examine the grain evolution of Cu-Sn IMCs, EBSD analysis was applied to microbumps and conventional-sized solder joints. Replacing the Cu substrate with Cu-Zn causes the grain orientation of Cu-Sn IMCs to become more random and dispersed, which may hinder crack propagation. It is thus expected that the reliability of Zn-doped microbumps and solder joints is superior to that of Cu substrate joints. © 2014 Elsevier B.V.

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