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Hidden lattice instabilities as origin of the conductive interface between insulating LaAlO3 and SrTiO3
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Hidden lattice instabilities as origin of the conductive interface between insulating LaAlO3 and SrTiO3

P.W. Lee, V.N. Singh, G.Y. Guo, H.-J. Liu, J.-C. Lin, Y.-H. Chu, C.H. ChenM.-W. Chu
Nature Communications, 卷.7, 12773
09/2016

摘要

Chemistry (all) Biochemistry Genetics and Molecular Biology (all) Physics and Astronomy (all)
The metallic interface between insulating LaAlO 3 and SrTiO 3 opens up the field of oxide electronics. With more than a decade of researches on this heterostructure, the origin of the interfacial conductivity, however, remains unsettled. Here we resolve this long-standing puzzle by atomic-scale observation of electron-gas formation for screening hidden lattice instabilities, rejuvenated near the interface by epitaxial strain. Using atomic-resolution imaging and electron spectroscopy, the generally accepted notions of polar catastrophe and cation intermixing for the metallic interface are discounted. Instead, the conductivity onset at the critical thickness of 4-unit cell LaAlO 3 on SrTiO 3 substrate is accompanied with head-to-head ferroelectric-like polarizations across the interface due to strain-rejuvenated ferroelectric-like instabilities in the materials. The divergent depolarization fields of the head-to-head polarizations cast the interface into an electron reservoir, forming screening electron gas in SrTiO 3 with LaAlO 3 hosting complementary localized holes. The ferroelectric-like polarizations and electron-hole juxtaposition reveal the cooperative nature of metallic LaAlO 3 /SrTiO 3 .

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https://doi.org/10.1038/ncomms12773檢視
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