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Hierarchical silicalite-1 octahedra comprising highly-branched orthogonally-stacked nanoplates as efficient catalysts for vapor-phase Beckmann rearrangement
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Hierarchical silicalite-1 octahedra comprising highly-branched orthogonally-stacked nanoplates as efficient catalysts for vapor-phase Beckmann rearrangement

Albert Chang, Hsu-Ming Hsiao, Tsai-Hsiu Chen, Ming-Wen Chu 和 Chia-Min Yang
Chemical Communications, 卷.52(80), 頁碼.11939-11942
2016
DOI: https://doi.org/10.1039/c6cc05992a

摘要

hierarchical zeolite;MFI zeolite;vapor-phase Beckmann rearrangement Catalysis Electronic Optical and Magnetic Materials Ceramics and Composites Chemistry (all) Surfaces Coatings and Films Metals and Alloys Materials Chemistry

A triblock structure-directing agent was designed to synthesize hierarchical silicalite-1 octahedra comprising highly-branched, orthogonally-stacked and self-pillared nanoplates that exhibited excellent and stable activity for the vapor-phase Beckmann rearrangement of cyclic oximes and high lactam selectivity.

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