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Highly regio- and stereoselective silylstannation of allenes catalyzed by phosphine-free palladium complexes
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Highly regio- and stereoselective silylstannation of allenes catalyzed by phosphine-free palladium complexes

Masilamani Jeganmohan, Muthian Shanmugasundaram, Kuo-Jui Chang and Chien-Hong Cheng
Chemical Communications, Vol.8(21), pp.2552-2553
2002

Abstract

The addition reaction of silylstannanes with allenes in the presence of Pd 2 (dba) 3 ·dba in toluene affords (E)-alkenylsilanes having an allylstannane moiety exclusively in good to excellent yields.
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