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Identifying Topological Defects in Lamellar Phases through Contour Analysis of Complex Wave Fields
Journal article   Peer reviewed

Identifying Topological Defects in Lamellar Phases through Contour Analysis of Complex Wave Fields

Chi-Huan Tung, Hsin-Lung Chen, Guan-Rong Huang, Lionel Porcar, Marianne Imperor, Jan-Michael Y. Carrillo, Yangyang Wang, Bobby G. Sumpter, Yuya Shinohara, Jon Taylor, …
Macromolecules, Vol.57(15), pp.6979-6989
13/08/2024

Abstract

Science & Technology Physical Sciences Polymer Science
Lamellar phases frequently contain structural imperfections that significantly affect their behaviors and properties. Our previous research successfully reconstructed real-space configurations of defective lamellar phases from diffuse scattering patterns, indicating the presence of phase vortices as a potential method for identifying topological defects disrupting the smectic ordering. This report presents a mathematical framework using regularized wave fields to represent defective lamellar structures in real space. Phase singularities, resulting from the interference of random waves and indicating lamellar order disruption, are identified through a contour integral. These wave fields, derived from coherent scattering in reciprocal space, were validated via computational benchmarks analyzing small-angle neutron scattering data from AOT surfactant solutions, facilitating further statistical analysis of the defects. Our study highlights the potential to extract meaningful information about topological defects in lyotropic phases by inversely analyzing experimentally measured two-point static correlations. Our method allows for detailed structural analysis of various lyotropic phases, both particulate and nonparticulate, in their quiescent states and facilitates quantitative investigation of defects' role in phase transitions. By integrating small-angle scattering, deep learning, and vortex tangle analysis, our comprehensive approach shows promise in addressing complex challenges in the structural analysis of soft matter systems.

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