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Improved Mass-Transfer Enhances Photo-Driven Dye Degradation and H2Evolution over a Few-Layer WS2/ZnO Heterostructure
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Improved Mass-Transfer Enhances Photo-Driven Dye Degradation and H2Evolution over a Few-Layer WS2/ZnO Heterostructure

Yu-Ju Huang, Lian-Ming Lyu, Cheng-Yi Lin, Guan-Chi Lee, Kai-Yuan HsiaoMing-Yen Lu
ACS Omega, 卷.7(2), 頁碼.2217-2223
01/2022

摘要

Chemistry (all) Chemical Engineering (all)
In this study, we observed the enhanced photocatalytic activity of a few-layer WS2/ZnO (WZ) heterostructure toward dye degradation and H2 production. The few-layer WS2 acted as a co-catalyst that separated photogenerated electron/hole pairs and provided active sites for reactions, leading to the rate of photocatalytic H2 production of WZ being 35% greater than that over the bare ZnO nanoparticles. Moreover, vortex-stirring accelerated the mass-transfer of the reactants, leading to the efficiency of dye photodegradation being 3 times higher than that obtained without high-speed stirring. We observed a similar effect for H2 production, with greater photocatalytic performance arising from the increased mass-transfer of H2 from the catalyst surface to the atmosphere.

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https://doi.org/10.1021/acsomega.1c05756檢視
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