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Improved Metal-Semiconductor Interface in Monolayer (1L)-MoS2 via Thermally-Driven Ag Filaments as Atomic Scale Edge Contacts Triggered by Selective Annealing Process Using Long Wavelength (1064 nm) Pulsed Laser
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Improved Metal-Semiconductor Interface in Monolayer (1L)-MoS2 via Thermally-Driven Ag Filaments as Atomic Scale Edge Contacts Triggered by Selective Annealing Process Using Long Wavelength (1064 nm) Pulsed Laser

Sumayah-Shakil Wani, Yao-Ren Kuo, K. Kimbulapitiya, Ruei-Hong Cyu, Chieh-Ting Chen, Ming-Jin Liu, Huynh-Uyen-Phuong Nguyen, Bushra Rehman, Xin-Rui Liu, Feng-Chuan Chuang, …
ACS Applied Materials and Interfaces, 卷.17(15), 頁碼.23209-23221
04/2025
PMID: 40178868

摘要

1064 nm Pulse laser annealing 2D materials atomic-scale edge contacts monolayer (1L)-MoS2 FET transition metal dichalcogenide Materials Science (all)
Here, we explore the effectiveness of a pulsed laser annealing (PLA) process to trigger atomic scale edge contacts by Ag filaments in reducing the contact resistance of a MoS 2 field-effect transistor (FET). Employing a long wavelength (1064 nm) pulsed laser, we anneal monolayer (1L)-MoS 2 FETs with various metal electrodes, including Ag/Au, Ni/Au, and Cr/Au. A remarkable enhancement in FET performance could be achieved after the PLA treatment. Specifically, Ag/Au-contacted 1L-MoS 2 FETs after the PLA treatment exhibit a peak field-effect mobility increase from 60 to 135 cm 2 V -1 s -1 and an on-current improvement from 40.5 to 96.1 μA at a Vd of 1 V, accompanied by a significant decrease in contact resistance to 0.29 kΩ μm. PLA-treated 1L-MoS 2 FETs showed a high on/off ratio of 10 7 . TEM analysis provided insight into the mechanism of reduced contact resistance, revealing the thermally driven diffusion of Ag atoms into the 1L-MoS 2 as Ag filaments to lateral contact with the edge of the 1L-MoS 2 , namely atomic scale edge contacts, as a key contributing factor. Furthermore, our investigation extends to the larger scale CVD-grown 1L-MoS 2 films, where the PLA treatment demonstrates notable improvements in mobility, on-current, and on-off ratio.

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