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In-situ synthesis of hydroxyapatite-supported Ag3PO4 using cockle (Anadara granosa) shell as photocatalyst in rhodamine B photodegradation and antibacterial agent
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In-situ synthesis of hydroxyapatite-supported Ag3PO4 using cockle (Anadara granosa) shell as photocatalyst in rhodamine B photodegradation and antibacterial agent

Is Fatimah, Rahmania Audita, Gani Purwiandono, Habibi Hidayat, Suresh Sagadevan, Won-Chun Oh and Ruey-an Doong
Case Studies in Chemical and Environmental Engineering, Vol.10, 100797
12/2024

Abstract

Ag3PO4 Antibacterial Hydroxyapatite Photocatalyst Photodegradation Environmental Engineering Environmental Chemistry Chemical Engineering (all) Environmental Science (miscellaneous) Engineering (miscellaneous)
A nanocomposite of hydroxyapatite-supported Ag 3 PO 4 (Ag 3 PO 4 / HA) was prepared by in-situ co-precipitation followed by hydrothermal method by utilizing cockle (Anadara granosa) shell as biogenic calcium source. The obtained nanocomposite was characterized by different instrumental analyses. X-ray diffraction spectroscopy, transmission electron microscopy, and X-ray photoelectron spectroscopy analyses confirmed the formation of dispersed Ag 3 PO 4 on HA structure with the particles size ranging at 10–40 nm. The material has band gap energy of 2.3 eV which support the activity as photocatalyst for rhodamine B degradation. The removal efficiency of 99.87% was expressed by the nanocomposite for 120 min of treatment, and reusability was demonstrated by insignificant change of the removal and kinetics constant for 5 cycles. The nanocomposite showed antibacterial activity against E. Coli, S. aureus, K. Pneumonia, and S. pyogenes.
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https://doi.org/10.1016/j.cscee.2024.100797View
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