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Influence of alloying and aging treatment on the strain hardening behavior of non-equiatomic CoCrFeNi high entropy alloy
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Influence of alloying and aging treatment on the strain hardening behavior of non-equiatomic CoCrFeNi high entropy alloy

Bushra Harun, E-Wen Huang, Yao-Jen Chang, An-Chou Yeh, Jayant JainSuresh Neelakantan
Intermetallics, 卷.181, 頁.108752
06/2025

摘要

Deformation mechanism High entropy alloys Precipitates Stacking faults Strain hardening behavior
The objective of the study was to investigate the work hardening behavior of AlxCo1.5CrFeNi1.5Tiy (where sum of x and y is 0.5, in atomic ratio and x = 0, 0.2, 0.3, 0.5) high entropy alloys (HEAs) in solutionized and peak-aged conditions. Work hardening behaviour was mainly driven by L12 and B2 precipitate formation, during aging, and the ease of stacking fault (SF) formation with varying Ti/Al concentrations. Increasing Ti concentration was found to decrease stacking fault energy (SFE), promoting SF formation and further enhanced work hardening. B2 precipitates contributed to Orowan looping-induced hardening, while L12 precipitates induced hardening through precipitate shearing via partial dislocations. Addition of Ti into the AlCoCrFeNi system induced a transition in the deformation mechanism from wavy slip to planar slip. Ordered domains formed during aging facilitate SF generation, resulting in higher work hardening rates. In addition, Taylor lattice-type deformation substructures were observed in the solutionized condition of Ti-containing alloys and were absent in their aged counterparts because precipitation facilitates the easy formation of SFs and hence decreases the propensity of Taylor lattices. Present study enhances the understanding of work hardening in various HEA compositions, aiding in the optimization of alloy design for structural materials. •Work hardening behavior of AlxCo1.5CrFeNi1.5Tiy high entropy alloys investigated.•Aging and increased Ti content result in an enhanced work hardening rate.•B2- and L12-precipitates respectively contribute to Orowan and shearing hardening mechanisms.•The tendency to form Taylor lattices diminishes with aging.•Ti alloying shifts the deformation mechanism from wavy slip to planar slip.

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