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Interface reactions and phase equilibrium between Ni/Cu under-bump metallization and eutectic SnPb flip-chip solder bumps
Journal article   Peer reviewed

Interface reactions and phase equilibrium between Ni/Cu under-bump metallization and eutectic SnPb flip-chip solder bumps

Chien-Sheng Huang and Jenq-Gong Duh
Journal of Materials Research, Vol.18(4), pp.935-940
04/2003

Abstract

Ni-based under-bump metallization (UBM) for flip-chip application is widely used in today's electronics packaging. In this study, electroplated Ni UBM with different thickness was used to evaluate the interfacial reaction during multiple reflow between Ni/Cu UBM and eutectic Sn-Pb solders in the 63Sn-37Pb/Ni/Cu/Ti/Si 3 N 4 /Si multilayer structure. During the first cycle of reflow, Cu atoms diffused through electroplated Ni and formed the intermetallic compound (IMC) (Ni 1-xM ,Cu x ) 3 Sn 4 . After more than three times of reflow, Cu atoms further diffused through the boundaries of (Ni 1-x ,Cu x ) 3 Sn 4 IMC and reacted with Ni and Sn to form another IMC of (Cu 1-y ,Ni y ) 6 Sn 5 . After detailed quantitative analysis by electron probe microanalysis, the values of y were evaluated to remain around 0.4; however, the values of x varied from 0.02 to 0.35. The elemental distribution of IMC in the interface of the joint assembly could be correlated to the Ni-Cu-Sn ternary equilibrium. In addition, the mechanism of (Cu 1-y ,Ni y ) 6 Sn 5 formation was also probed.

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