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Interfacial reactions in In-Sn/Ni couples and phase equilibria of the In-Sn-Ni system
Journal article   Peer reviewed

Interfacial reactions in In-Sn/Ni couples and phase equilibria of the In-Sn-Ni system

Sinn-Wen Chen
Journal of Electronic Materials, Vol.31(2), pp.152-160
02/2002

Abstract

In-Sn Interfacial reactions Lead-free solder Ni Phase equilibria
The In-Sn-Ni alloys of various compositions were prepared and annealed at 160°C and 240°C. No ternary compounds were found; however, most of the binary compounds had extensive ternary solubility. There was a continuous solid solution between the Ni 3 Sn phase and Ni 3 In phase. The Sn-In/Ni couples, made of Sn-In alloys with various compositions, were reacted at 160°C and 240°C and formed only one compound for all the Sn-In alloys/Ni couples reacted up to 8 h. At 240°C, Ni 28 In 72 phase formed in the couples made with pure indium, In-10at.%Sn and In-11at.%Sn alloys, while Ni 3 Sn 4 phase formed in the couples made of alloys with compositions varied from pure Sn to In-12at.%Sn. At 160°C, except in the In/Ni couple, Ni 3 Sn 4 formed by interfacial reaction.

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