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Ion-size effect on normal-state transport properties in R0.8Pr0.2Ba2Cu3O7-y systems (R=Yb, Er, Dy, Gd, Eu, and Nd)
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Ion-size effect on normal-state transport properties in R0.8Pr0.2Ba2Cu3O7-y systems (R=Yb, Er, Dy, Gd, Eu, and Nd)

J.C. Chen, Yunhui Xu, M.K. Wu and Weiyan Guan
Physical Review B - Condensed Matter and Materials Physics, Vol.53(9), pp.5839-5847
01/03/1996

Abstract

We report detailed studies of the normal-state resistivity and the Hall-effect in bulk R 0.8 Pr 0.2 Ba 2 Cu 3 O 7-y samples (R=Yb, Er, Dy, Gd, Eu, and Nd). We find a linear temperature dependence of the normal-state resistivity p u and the Hall number n H above T c . in these systems. At a constant temperature both p n and n H are linearly dependent on the ion-size of the rare earth, viz., the larger R 3+ ionic radius, the larger p n , but the lower n H . The cotangent of the Hall angle follows a universal T 2 dependence, i.e., cotθ H =αT 2 +C. Both the slope α and the quantity C is insensitive to the R ion and remains almost constant. On the basis of our data we propose a T c -n H diagram which manifests an "underdoping" behavior of R 0.8 Pr 0.2 Ba 2 Cu 3 O 7-y systems. We suggest that the strong hybridization between the 4f states of the Pr ion and the conduction-band states in CuO 2 planes, leading to hole localization and pair breaking, are the mechanism for the suppression of superconductivity in R 1-x Pr x Ba 2 Cu 3 O 7-y systems.

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