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Irradiation Damage Independent Deuterium Retention in WMoTaNbV
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Irradiation Damage Independent Deuterium Retention in WMoTaNbV

Anna Liski, Tomi Vuoriheimo, Pasi Jalkanen, Kenichiro Mizohata, Eryang Lu, Jari Likonen, Jouni Heino, Kalle Heinola, Yevhen Zayachuk, Anna Widdowson, …
Materials, 卷.15(20), 7296
10/2022

摘要

deuterium elastic recoil fusion high entropy alloy hydrogen metals secondary ion thermal desorption Materials Science (all) Condensed Matter Physics
High entropy alloys are a promising new class of metal alloys with outstanding radiation resistance and thermal stability. The interaction with hydrogen might, however, have desired (H storage) or undesired effects, such as hydrogen-induced embrittlement or tritium retention in the fusion reactor wall. High entropy alloy WMoTaNbV and bulk W samples were used to study the quantity of irradiation-induced trapping sites and properties of D retention by employing thermal desorption spectrometry, secondary ion mass spectrometry, and elastic recoil detection analysis. The D implantation was not found to create additional hydrogen traps in WMoTaNbV as it does in W, while 90 at% of implanted D is retained in WMoTaNbV, in contrast to 35 at% in W. Implantation created damage predicted by SRIM is 0.24 dpa in WMoTaNbV, calculated with a density of (Formula presented.) atoms/cm (Formula presented.). The depth of the maximum damage was 90 nm. An effective trapping energy for D in WMoTaNbV was found to be about 1.7 eV, and the D emission temperature was close to 700 °C.

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