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Liquidus projection and miscibility gap of the Ag-Cu-Te ternary system
期刊文章

Liquidus projection and miscibility gap of the Ag-Cu-Te ternary system

信文 陳, Pin-shuo Huang, Yung-Chun TsaiYohanes Hutabalian
Calphad-Computer Coupling of Phase Diagrams and Thermochemistry, 卷.87(19), 頁.102765
12/2024

摘要

Ag-Cu-Te;Liquidus projection;Liquid miscibility gap;Spherical-shape microstructure

Ag-Cu-Te is a significant material system, and experimental measurements have been conducted to determine its liquidus projection. Aside from the terminal solid solution phases and binary compounds, there exists a ternary compound known as AgCuTe. The ten primary solidification phases include (Ag), Ag2Te, Ag1.9Te, Ag5Te3, (Te), CuTe, Cu3Te2, Cu2Te, (Cu), and AgCuTe. A liquid miscibility gap with a very wide compositional range is observed. When the alloys are at temperatures higher than those of the binodal curves, they are entirely molten. Interesting spherical-shaped microstructures are observed when the alloys solidify passing through the liquid miscibility gap. Furthermore, it has been determined that there are nine invariant reactions, consisting of three Class I reactions (L ↔ α + β + γ) three Class II reactions (L + α ↔ β + γ), and three Class III reactions (L + α + β ↔ γ). The highest and lowest invariant reaction temperatures are determined to be 849.0 °C and 308.0 °C, respectively.

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