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Low temperature process for synthesis of (100) textured Pb(Zr 0.48Ti0.52)O3 thin films on Si substrate by laser lift-off transferring technique
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Low temperature process for synthesis of (100) textured Pb(Zr 0.48Ti0.52)O3 thin films on Si substrate by laser lift-off transferring technique

Ying-Hao Chu, Su-Jien Lin, Kuo-Shung LiuI.-Nan Lin
Integrated Ferroelectrics, 卷.57, 頁碼.1233-1240
2003

摘要

Laser-lift-off process Low temperature process Pb(Zr,Ti)O3 thin films Electrical and Electronic Engineering Physics and Astronomy (miscellaneous) Condensed Matter Physics Electronic Optical and Magnetic Materials
(100) textured Pb(Zr 0.48 Ti 0.52 )O 3 (PZT) films were prepared on silicon substrates by MOD process and laser lift-off technique. Textured PZT films were first grown on (001) Sapphire substrate, using Ba(Mg 1/3 Ta 2/3 )O 3 (BMT) materials as buffer layer. The (100) textured PZT/BMT/Sapphire films were attached to Si substrate using a transient-liquid-phase Pd-In bonding process, and then were separated from Sapphire substrates by a laser lift-off process, in which, a 38 ns pulse from excimer laser (248 nm) at 600 mJ/cm 2 fluence melted BMT buffer layer, expelling the Sapphire. The crystallinity of the surface of films was further improved by laser annealing. X-ray diffraction analysis of the PZT films showed that the crystallographic structure of films is maintained during laser lift-off process. Electrical testing of the films after laser lift-off process followed by laser annealing demonstrated that the ferroelectric properties are retained for the transferred films (P r = 9μ C/cm 2 and E c = 74 kV/cm).

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