Magnetic isotope effects in biradicals: Substantial 13C enrichment and a novel mechanistic probe

Nicholas J. Turro; Charles Doubleday Jr.; Kuo-Chu Hwang; Chen-Chih Cheng; James R. Fehlner

doi:10.1016/S0040-4039(00)96246-4

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Magnetic isotope effects in biradicals: Substantial 13C enrichment and a novel mechanistic probe

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Magnetic isotope effects in biradicals: Substantial 13C enrichment and a novel mechanistic probe

Nicholas J. Turro, Charles Doubleday Jr., Kuo-Chu Hwang, Chen-Chih Cheng and James R. Fehlner

Tetrahedron Letters, Vol.28(26), pp.2929-2932

1987

DOI: https://doi.org/10.1016/S0040-4039(00)96246-4

Abstract

Photolysis of 2,n-diphenylcycloalkanones (n-membered ring, n = 10, 11, 12, 15) produces products that are significantly enriched in ¹³ C. The enrichments are different for each product, and this allows assignment of the dynamic pathways through which each product is formed. © 1987.

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Title: Magnetic isotope effects in biradicals: Substantial 13C enrichment and a novel mechanistic probe
Creators - without role: Nicholas J. Turro - Columbia University
Charles Doubleday Jr. - Columbia University
Kuo-Chu Hwang - Columbia University
Chen-Chih Cheng - Columbia University
James R. Fehlner - Columbia University
Publication Details: Tetrahedron Letters, Vol.28(26), pp.2929-2932
Identifiers: 9957768366006774
Academic Unit: Institute of Analytical and Environmental Sciences, College of Nuclear Science, National Tsing Hua University
Language: English
Resource Type: Journal article

Magnetic isotope effects in biradicals: Substantial 13C enrichment and a novel mechanistic probe

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