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Mechanism of Fe-Mn-Al alloy steel ingot failure from MgO-C refractory corrosion
Journal article   Peer reviewed

Mechanism of Fe-Mn-Al alloy steel ingot failure from MgO-C refractory corrosion

Jyh-Wei Lee and Jenq-Gong Duh
Journal of Materials Science, Vol.38(4), pp.713-720
15/02/2003

Abstract

Fe-Mn-Al alloy steel was melted in a mass production tonnage arc furnace equipped with ladle refining facilities. The ingots were cracked and torn apart on hot rolling. Blue flames erupted from the cracks and became red. A white powder was observed adjacent to the cracks in ingots. The white powder was identified as magnesia. Concentrations of Mg and Ca were high in the centre of the ingot, implying the segregation of impurities. Quantitative elemental analysis and microstructural investigation revealed Mg, Si, Ca and S containing impurities and Cr, Mo and Si carbides were segregated within grain boundaries. The segregation was the main cause of ingot cracking. The 1600°C static cup test for carbon containing MgO-C refractories exhibited the reduction reaction, which raised the Mg concentration up to 0.017 wt% in Fe-Mn-Al alloy steel, whereas the pure MgO refractory cup test showed inertness to Fe-Mn-Al alloy.

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