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Molecular architecture towards helical double-stranded polymers
Journal article   Open access   Peer reviewed

Molecular architecture towards helical double-stranded polymers

Hui-Chun Yang, Shu-Yi Lin, Hsiao-Ching Yang, Cheng-Lan Lin, Lun Tsai, Shou-Ling Huang, I. Wen-Peter Chen, Chun-Hsien Chen, Bih-Yaw Jin and Tien-Yau Luh
Angewandte Chemie - International Edition, Vol.45(5), pp.726-730
01/2006
PMID: 16381039

Abstract

Helical structures Metathesis Molecular modeling Ring-opening polymerization Scanning probe microscopy Catalysis Chemistry (all)
(Figure Presented) Close to original: A DNA-like double-stranded polymer is synthesized by ring-opening metathesis polymerization of a bisnorbornene derivative containing a rigid ferrocene spacer. The polymer forms helices (see picture), supercoils, and ladders, which are observable by scanning tunneling microscopy. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
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https://doi.org/10.1002/mrc.1830View
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