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Nitrene Transfer and Carbene Transfer in Gold Catalysis
   

Nitrene Transfer and Carbene Transfer in Gold Catalysis

Long-Wu Ye, Xin-Qi Zhu, Rajkumar Lalji Sahani, Yin Xu, Peng-Cheng Qian Rai-Shung Liu
Chemical Reviews
28/07/2021
: https://doi.org/10.1021/acs.chemrev.0c00348
: WOS:000679894900014
Chemistry (all)
Catalytic transformations involving metal carbenes are considered one of the most important aspects of homogeneous transition metal catalysis. Recently, gold-catalyzed generation of gold carbenes from readily available alkynes represents a significant advance in metal carbene chemistry. This Review summarizes the advances in the gold-catalyzed nitrene-transfer reactions of alkynes with nitrogen-transfer reagents, such as azides, nitrogen ylides, isoxazoles, and anthranils, and gold-catalyzed carbene-transfer reactions, involving oxygen atom-transfer reactions of alkynes with nitro compounds, nitrones, sulfoxides, and pyridine N-oxides, through the presumable α-imino gold carbene and α-oxo gold carbene intermediates, respectively. Gold-catalyzed processes are reviewed by highlighting their product diversity, selectivity, and applicability, and the mechanistic rationale is presented where possible.

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2 Chemistry
2.1 Synthesis
2.1.902 Metal-Catalyzed Cyclizations
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Chemistry, Multidisciplinary
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Chemistry
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