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Nonlinear vibrational spectroscopy on rubbed polymer surfaces
Journal article

Nonlinear vibrational spectroscopy on rubbed polymer surfaces

X. Wei, D. Kim, M. O-He and Y.R. Shen
Molecular Crystals and Liquid Crystals Science and Technology Section B: Nonlinear Optics, Vol.25(1-4), pp.13-22
2000

Abstract

Control and Systems Engineering Condensed Matter Physics
Sum-frequency vibrational spectroscopy is an effective tool for probing polymer surfaces and interfaces. This is demonstrated here by its application on rubbed polymer surfaces. The spectroscopic results show that rubbing preferentially aligns the surface polymer chains along the rubbing direction. The modified polymer surface then acts as a template to align the liquid crystal molecules adsorbed on it.

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