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Orientations of side chains and adsorbed liquid crystal molecules on a rubbed polyimide surface studied by optical second harmonic generation
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Orientations of side chains and adsorbed liquid crystal molecules on a rubbed polyimide surface studied by optical second harmonic generation

Seok-Cheol Hong, Masahito Oh-E, Xiaowei Zhuang, Q. Shen, Jason J. Ge, B.W. HarrisS.Z.D. Cheng
Physical Review E - Statistical, Nonlinear, and Soft Matter Physics, 卷.63(5 I), 頁碼.517061-517067
2001

摘要

Statistical and Nonlinear Physics Statistics and Probability Condensed Matter Physics
The orientational distributions of the side chains and the adsorbed liquid crystal (LC) molecules on a rubbed side-chain polyimide surface were found by surface second harmonic generation. The side chains and the main chains were found to be aligned along the rubbing direction. The side chains were bent with the free terminals pointing towards the surface. The side chains and the LC molecules were found to have antiparallel orientations at the surface.

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