摘要
We demonstrate a simple but effective method to control the orientation of silver nanowires (AgNWs). Shear-flow-induced AgNW preferable orientation is realized by judiciously controlling the process parameters in the bar-coating method. This controllability of the NW direction enables the formation of AgNW cross-linking networks for transparent conductive electrode (TCE) applications. We experimentally demonstrate that the orthogonally weaved AgNW networks possess predominant advantages of lower percolation limit, higher transmission, and lower sheet resistance compared with the randomly orientated AgNW counterparts. The phenomenon is also confirmed with theoretical calculation by the Monte Carlo method. These high-quality AgNW TCEs exhibit a high transmittance of ∼94% with a sheet resistance of ∼20 Ω/sq, which meet the requirements of modern optoelectronic devices. Very efficient organic light-emitting diodes (OLEDs) and organic solar cells (OSCs) prepared by these AgNW TCEs are demonstrated. The OLED exhibits exceptionally high luminance efficiency, power efficacy, and external quantum efficiency of 92 cd/A, 111 lm/W, and 26.8%, respectively. The OSCs also deliver a high power conversion efficiency of up to 7.5%.