Palladium-catalyzed cyclization of alkenyl and aryl halides containing α, β-Unsaturated carbonyl groups via intramolecular carbopalladation

Brian O'Connor; Yantao Zhang; Ei-ichi Negishi; Fen-Tair Luo; Jya-Wei Cheng

doi:10.1016/S0040-4039(00)80376-7

Palladium-catalyzed cyclization of alkenyl and aryl halides containing α, β-Unsaturated carbonyl groups via intramolecular carbopalladation

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Palladium-catalyzed cyclization of alkenyl and aryl halides containing α, β-Unsaturated carbonyl groups via intramolecular carbopalladation

Brian O'Connor, Yantao Zhang, Ei-ichi Negishi, Fen-Tair Luo 和 Jya-Wei Cheng

Tetrahedron Letters, 卷.29(32), 頁碼.3903-3906

1988

DOI: https://doi.org/10.1016/S0040-4039(00)80376-7

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Biochemistry

Drug Discovery

Organic Chemistry

Treatment of alkenyl and aryl iodides and bromides containing an appropriate α, β-unsaturated carbonyl group with a catalytic amount (3-5 mol %) of either a Pd(O) or a Pd(II) complex, e.g., Pd(PPh ₃ ) ₄ , and a base, e.g., NEt ₃ , can induce highly regioselective cyclization via intramolecular carbopalladation; formation of exocyclic alkenes can also be highly stereoselective. © 1988.

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題名: Palladium-catalyzed cyclization of alkenyl and aryl halides containing α, β-Unsaturated carbonyl groups via intramolecular carbopalladation
創作者：: Brian O'Connor (作者) - Department of Chemistry, Purdue University
Yantao Zhang (作者) - Department of Chemistry, Purdue University
Ei-ichi Negishi (作者) - Department of Chemistry, Purdue University
Fen-Tair Luo (作者) - Institute of Chemistry, Academia Sinica
Jya-Wei Cheng (作者) - Institute of Chemistry, Academia Sinica
學術資源類型: 期刊文章
出版日期: 1988
出版資訊: Tetrahedron Letters, 卷.29(32), 頁碼.3903-3906
語言: 英語

Palladium-catalyzed cyclization of alkenyl and aryl halides containing α, β-Unsaturated carbonyl groups via intramolecular carbopalladation

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