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Phase Equilibria and Thermodynamic Descriptions of Ag-Ge and Ag-Ge-Ni Systems
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Phase Equilibria and Thermodynamic Descriptions of Ag-Ge and Ag-Ge-Ni Systems

V.B. RajkumarSinn-Wen Chen
Journal of Electronic Materials, 卷.47(7), 頁碼.3666-3677
07/2018

摘要

calculation of phase diagram (Calphad),Differential thermal analysis (DTA),electron probe micro-analysis (EPMA),special quasi random structures (SQS),Vienna ab initio simulation package (VASP),x-ray diffraction (XRD) Electronic Optical and Magnetic Materials Condensed Matter Physics Electrical and Electronic Engineering Materials Chemistry
Gibbs energy modeling of Ag-Ge and Ag-Ge-Ni systems was done using the calculation of the phase diagram method with associated data from this work and relevant literature information. In the Ag-Ge system, the solidus temperatures of Ag-rich alloys are measured using differential thermal analysis, and the energy of mixing for the FCC_A1 phase is calculated using the special quasi-random structures technique. The isothermal sections of the Ag-Ge-Ni system at 1023 K and 673 K are also experimentally determined. These data and findings in the relevant literature are used to model the Gibbs energy of the Ag-Ge and Ag-Ge- Ni systems. A reaction scheme and a liquidus projection of the Ag-Ge-Ni system are determined.

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