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Phase diagram of Pb–Se–Te system I: Experimental study
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Phase diagram of Pb–Se–Te system I: Experimental study

Sinn-wen Chen, Tse-yang Huang, Ya-Hsiang Hsu, Jun-Xiang Liu, A. ZemanovaAleš Kroupa
Calphad: Computer Coupling of Phase Diagrams and Thermochemistry, 卷.74, 102310
09/2021

摘要

Pb-Se-Te Phase diagram Chemistry (all) Chemical Engineering (all) Computer Science Applications
Pb–Se–Te ternary system is of significant importance for thermoelectric applications. However, no systematic study of its phase diagram has been carried until now. Samples of Pb–Se–Te ternary alloys were prepared, their phase equilibrium phases were determined, and the Pb–Se–Te isothermal sections at 350 °C and 500 °C were proposed based on the experimental results. No ternary compounds were found. There is one three phase field, Pb(Se,Te)+liquid(Se,Te)+(Se,Te) at 350 °C and no three phase field at 500 °C. PbSe and PbTe form a continuous solid solution at both temperatures.

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