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Photocatalytic enhancement of hydrogen production in water splitting under simulated solar light by band gap engineering and localized surface plasmon resonance of ZnxCd1-xS nanowires decorated by Au nanoparticles
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Photocatalytic enhancement of hydrogen production in water splitting under simulated solar light by band gap engineering and localized surface plasmon resonance of ZnxCd1-xS nanowires decorated by Au nanoparticles

Yu-Cheng Chen, Yu-Sheng Huang, Han Huang, Po-Jui SuTsong-Pyng Perng
Nano Energy, 104225
2019

摘要

Au nanoparticles Band gap engineering Hydrogen production Localized surface plasmon resonance Photocatalytic ZnxCd1-xS nanowires Renewable Energy Sustainability and the Environment Materials Science (all) Electrical and Electronic Engineering
Excellent photocatalytic properties for hydrogen production in water splitting under simulated solar light (with AM1.5G filter) with Au nanoparticles (NPs)/Zn Cd S nanowires (NWs) have been demonstrated. The Zn Cd S NWs photocatalyst shows much higher photocatalytic activity for H -production than ZnS and CdS NWs with Na S and Na SO as sacrificial reagents. The high photocatalytic H -production activity, as high as 57.07 mmol g h , is attributed to appropriate band gap width and suitable conduction band edge potential of the Zn Cd S NWs. The H -production efficiency was further significantly enhanced to 96.04 mmol g h by decorating Zn Cd S NWs with appropriate size and distribution of Au NPs to induce localized surface plasmon resonances (LSPR) in visible and near infrared region. The work represents significant advance with a totally green and novel approach of enhancing H -production efficiency in water splitting under simulated solar light (with AM1.5G filter).

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