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Photocatalytic generation of H2 gas from neat ethanol over Pt/TiO2 nanotube catalysts
期刊文章

Photocatalytic generation of H2 gas from neat ethanol over Pt/TiO2 nanotube catalysts

C.-H. Lin, C.-H. Lee, J.-H. Chao, C.-Y. Kuo, Y.-C. Cheng, W.-N. Huang, H.-W. Chang, Y.-M. HuangM.-K. Shih
Catalysis Letters, 卷.98(1), 頁碼.61-66
10/2004

摘要

Dehydrogenation Ethanol Hydrogen, photocatalytic Tio2 nanotube Catalysis Chemistry (all)
TiO nanotubes promoted with Pt metal were prepared and tested to be the photocatalytic dehydrogenation catalyst in neat ethanol for producing H gas (C H OH → C CHO + H ). It was found that the ability to produce H , the liquid phase product distribution and the catalyst stability of these promoted nano catalysts all depended on the Pt loading and catalyst preparation procedure. These Pt/TiO catalysts with TiO nanotubes washed with diluted H SO solution produced 1, 2-diethoxy ethane (acetal) as the major liquid phase product, while over those washed with diluted HCl solution or H O, acetaldehyde was the major liquid phase product.

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