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Photocatalytic redox-combined synthesis of l-pipecolinic acid with a titania-modified microchannel chip
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Photocatalytic redox-combined synthesis of l-pipecolinic acid with a titania-modified microchannel chip

Go Takei, Takehiko KitamoriHaeng-Boo Kim
Catalysis Communications, 卷.6(5), 頁碼.357-360
05/2005

摘要

Catalysis Chemistry (all) Process Chemistry and Technology
A titania-modified microchannel chip (TMC) was fabricated to implement an efficient photocatalytic synthesis of l-pipecolinic acid from l-lysine. The conversion rate in the chip was 70 times larger than that in a cuvette using nm-sized titania particles with almost the same selectivity and enantiomeric excess. The results showed that TMC had satisfactory potential to allow its application to photocatalytic synthesis as well as photodegradation. © 2005 Elsevier B.V. All rights reserved.

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