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Platinum-Free Ternary Metallic Selenides as Nanostructured Counter Electrode for High-Efficiency Dye-Sensitized Solar Cell by Interface Engineering
期刊文章

Platinum-Free Ternary Metallic Selenides as Nanostructured Counter Electrode for High-Efficiency Dye-Sensitized Solar Cell by Interface Engineering

Wen-Wu Liu, Wei Jiang, Yu-Cheng Liu, Wen-Jun Niu, Mao-Cheng Liu, Kun Zhao, Lu-Yin Zhang, Ling Lee, Ling-Bin KongYu-Lun Chueh
ACS Applied Energy Materials
2020

摘要

dye-sensitized solar cells electrocatalyst matched work function reduced interface resistance synergistic effect ternary alloy selenides Chemical Engineering (miscellaneous) Energy Engineering and Power Technology Electrochemistry Materials Chemistry Electrical and Electronic Engineering
The high cost and instability of platinum (Pt) counter electrodes (CEs) are two persistent issues in dye-sensitized solar cells (DSSCs). Here, ternary selenide NiCoSe and RuCoSe-nanostructured CEs are prepared by a simple one-step hydrothermal method. We mainly investigate the synergistic effect of ternary transition metals on the electrocatalytic properties. As a result, the photoelectric conversion efficiency (PCE) of NiCoSe CEs DSSCs with the enhanced efficiency up to 8.19% can be achieved. The excellent catalytic properties of the NiCoSe alloy selenide on I can be attributed to the expanded active sites, matched work function, redistributed electron structures, and reduced interface resistance. The facile preparation approach and outstanding catalytic behaviors offer applications of available DSSCs with low cost, superior stability, and promising performance.

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