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Poly[(μ6-benzene-1,3,5-tricarboxylato-κ6 O1:O1′:O3:O3′:O 5:O5′)tris(N,N-dimethylformamide-κO) tris(μ3-formato-κ2O:O′)trimagnesium(II)]
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Poly[(μ6-benzene-1,3,5-tricarboxylato-κ6 O1:O1′:O3:O3′:O 5:O5′)tris(N,N-dimethylformamide-κO) tris(μ3-formato-κ2O:O′)trimagnesium(II)]

Chun-Ting Yeh, Hsin-Kuan Liu, Chia-Jing LinChia-Her Lin
Acta Crystallographica Section E: Structure Reports Online, 卷.66(10)
10/2010

摘要

Chemistry (all) Materials Science (all) Condensed Matter Physics
The title complex, [Mg 3 (CHO 2 ) 3 (C 9 H 3 O 6 )(C 3 H 7 NO) 3 ] n , exhibits a two-dimensional structure parallel to (001), which is built up from the Mg II atoms and bridging carboxyl-ate ligands (3 symmetry). The Mg II atom is six-coordinated by one O atom from a dimethyl-formamide molecule, two O atoms from two μ 6 -benzene-1,3,5-tricarboxyl-ate ligands and three O atoms from three μ 3 -formate ligands in a distorted octa-hedral geometry.

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https://doi.org/10.1107/S1600536810035907檢視
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