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Poly[[aqua(μ5 -3,4,5,6-tetracarboxycyclohexane-1,2- dicarboxylato)strontium] monohydrate]
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Poly[[aqua(μ5 -3,4,5,6-tetracarboxycyclohexane-1,2- dicarboxylato)strontium] monohydrate]

Pei-Chi Cheng, Jun-Xiang Zhan, Cheng-You WuChia-Her Lin
Acta Crystallographica Section E: Structure Reports Online, 卷.67(12)
12/2011

摘要

data-to-parameter ratio = 14.8 mean σ(C-C) = 0.003 Å R factor = 0.028 single-crystal X-ray study T = 296 K wR factor = 0.065 Chemistry (all) Materials Science (all) Condensed Matter Physics
In the title compound, {[Sr(C 12 H 10 O 12 )(H 2 O)]·H 2 O} n , the Sr II ion is coordinated by six O atoms of five symmetry-related 3,4,5,6-tetracarboxycyclohexane-1,2-dicarboxylate ligands and one water mol-ecule in a slightly distorted monocapped trigonal-prismatic environment. The ligands bridge the Sr II ions, forming a two-dimensional structure. In the crystal, O-H⋯O hydrogen bonds further connect the structure into a three-dimensional network. The H atoms of two of the carboxyl groups were refined as half-occupancy.

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