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Poly[diaqua-μ4-biphenyl-4,4′-dicarboxyl-ato- magnesium(II)]
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Poly[diaqua-μ4-biphenyl-4,4′-dicarboxyl-ato- magnesium(II)]

Hsin-Kuan Liu, Xiang-Wen PengChia-Her Lin
Acta Crystallographica Section E: Structure Reports Online, 卷.65(2)
2009

摘要

Chemistry (all) Materials Science (all) Condensed Matter Physics
The solvothermal reaction of magnesium nitrate with bi-phenyl-4,4′- dicarboxylic acid in N,N-dimethyl-formamide and water leads to the formation of crystals of the title complex, [Mg(C14H8O4)(H2O)2] n. In the crystal structure, the Mg cations are coordinated by six O atoms from two water mol-ecules and four symmetry-related biphenyl-4,4′-dicarboxyl-ate anions within slightly distorted octa-hedra. The Mg cations are located on a center of inversion, the biphenyl-4,4′-dicarboxyl-ate anions around a twofold rotation axis and the water mol-ecule in a general position. The Mg cations are linked by the anions into a three-dimensional framework.

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