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Poly(methacrylate)-derived diblock dispersant for TiO2 in aqueous suspensions
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Poly(methacrylate)-derived diblock dispersant for TiO2 in aqueous suspensions

Chia-Chen Li, Shinn-Jen Chang, Chi-Wei WuCha-Wen Chang
Journal of the American Ceramic Society, 卷.100(11), 頁碼.4961-4964
11/2017

摘要

dispersants/dispersion processing suspensions tape casting titanium oxide Ceramics and Composites Materials Chemistry
In this paper, we propose a newly designed dispersant, ammonium poly(methacrylate)-block-poly(2-phenoxyethyl acrylate) (PMA-b-PBEA), and our rheological and zeta potential test results verify its superior dispersion efficiency for aqueous suspensions in comparison to the commercial dispersant ammonium polyacrylate (PAA-NH 4 ). The extremely high dispersion efficiency of PMA-b-PBEA correlates closely to its diblock structure, which simultaneously exhibits a less polar anchoring head group and a water-dissociable stabilizing moiety. The unique structure of PMA-b-PBEA accounts for its high powder adsorption effectiveness, which is demonstrated in its adsorption capability being double that of PAA-NH 4 .

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