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Preliminary evaluation of SEM/EDS technique for the determination of colloid diffusion coefficient in granite matrix
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Preliminary evaluation of SEM/EDS technique for the determination of colloid diffusion coefficient in granite matrix

Tsuey-Lin Tsai, Yu-Hung Shih, Liang-Cheng Chen, Shih-Chin Tsai, I-Hsien Lee, Chuan-Pin Lee 和 Te-Yen Su
Journal of radioanalytical and nuclear chemistry, 卷.322(3), 頁碼.1803-1808
01/12/2019
Web of Science ID: WOS:000493651700007

摘要

Chemistry Chemistry, Analytical Chemistry, Inorganic & Nuclear Nuclear Science & Technology Physical Sciences Science & Technology Technology
Colloids present high sorption for many solutes and are considered potential contaminant carriers in geological environments. Experimental quantitative data are required for an adequate description of colloid-mediated transport within natural media. In this paper, the line scan function of SEM/EDS was firstly applied to study colloid diffusion by depth profile in crystalline rock and the apparent diffusion coefficient was estimated to be similar to 6E-18 m(2)/s for 20 nm gold colloids. This technique can be applied to the prediction of colloid-facilitated radionuclide transport through water-saturated fractured porous rock for safety assessment of geological disposal for high-level radioactive waste.

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