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Probing Critical Point Energies of Transition Metal Dichalcogenides: Surprising Indirect Gap of Single Layer WSe2
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Probing Critical Point Energies of Transition Metal Dichalcogenides: Surprising Indirect Gap of Single Layer WSe2

Chendong Zhang, Yuxuan Chen, Amber Johnson, Ming-Yang Li, Lain-Jong Li, Patrick C. Mende, Randall M. FeenstraChih-Kang Shih
Nano Letters, 卷.15(10), 頁碼.6494-6500
10/2015
PMID: 26389585

摘要

critical points in Brillouin zones interlayer coupling scanning tunneling spectroscopy spin-orbit coupling Transition metal dichalcogenides variable Z spectroscopy Bioengineering Chemistry (all) Materials Science (all) Condensed Matter Physics Mechanical Engineering
By using a comprehensive form of scanning tunneling spectroscopy, we have revealed detailed quasi-particle electronic structures in transition metal dichalcogenides, including the quasi-particle gaps, critical point energy locations, and their origins in the Brillouin zones. We show that single layer WSe 2 surprisingly has an indirect quasi-particle gap with the conduction band minimum located at the Q-point (instead of K), albeit the two states are nearly degenerate. We have further observed rich quasi-particle electronic structures of transition metal dichalcogenides as a function of atomic structures and spin-orbit couplings. Such a local probe for detailed electronic structures in conduction and valence bands will be ideal to investigate how electronic structures of transition metal dichalcogenides are influenced by variations of local environment.

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