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Quantum well electronic states in spatially decoupled 2D Pb nanoislands on Nb-doped SrTiO3(0 0 1)
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Quantum well electronic states in spatially decoupled 2D Pb nanoislands on Nb-doped SrTiO3(0 0 1)

Guan-Yu Chen, Chia-Hsiu Hsu, Bo-You Liu, Li-Wei Chang, Deng-Sung Lin, Feng-Chuan ChuangPin-Jui Hsu
Applied Surface Science, 卷.537, 147967
01/2021

摘要

2D Pb nanoislands High-temperature superconductivity Phase accumulation model Quantum well states Scanning tunneling spectroscopy Chemistry (all) Condensed Matter Physics Physics and Astronomy (all) Surfaces and Interfaces Surfaces Coatings and Films
Two-dimensional (2D) Pb nanoisland has established an ideal platform for studying the quantum size effects on growth mechanism, electronic structures as well as high-temperature superconductivity. Here, we investigate the growth and quantum well electronic states of the 2D Pb nanoislands on Nb-doped SrTiO 3 (0 0 1) by scanning tunneling microscopy and spectroscopy. In contrast to Pb/Si(1 1 1), Pb/Cu(1 1 1) and Pb/Ag(1 1 1), there is no wetting layer of Pb formed on the Nb-doped SrTiO 3 (0 0 1) surface, resulting in isolated Pb nanoislands with an apparent height of 4 atomic layers as the building blocks for the island growth. According to the thickness-dependent quantum well states resolved in both occupied and unoccupied energy regions, the constant group velocity v g = 1.804 × 10 6 m/s and the Fermi wavevector k F = 1.575 Å −1 , have been extracted from a linear fit of the Pb(1 1 1) band dispersion along the Γ-L direction. In addition, the energy-dependent scattering phase shift φ(E) obtained by means of the phase accumulation model shows a metallic-like scattering interface analogous to Pb/Ag(1 1 1). These spatially decoupled 2D Pb nanoislands thus realize an opportunity to explore the intrinsic quantum confinement phenomena in nanoscale superconductors on the doped titanium-oxide-type substrate.

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