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Quencher-free optical recording materials: Photofading experimental and antiphotofading mechanism studies
Journal article   Peer reviewed

Quencher-free optical recording materials: Photofading experimental and antiphotofading mechanism studies

Wen-Yih Liao, Ming Chia Li, Andrew Teh Hu and Sanboh Lee
Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers, Vol.42(6 A), pp.3447-3451
06/2003

Abstract

3T CNR Antiphotofading CD-R DVD-R TCNQ Two-step photoinduced electron transfer (two-step PET)
In the experiment of antiphotofading of DVD-R optical recording disc, a 3000 W xenon light (λ = 420 nm) was adopted for testing the parameters of a novel cyanine-TCNQ (tetracyanoquinodimethane) charge transfer complex as a recording layer. Its performance without addition of a singlet oxygen quencher under illumination of 1200 min still satisfies with the DVD-R media requirements (3T CNR ≧ 45 dB; Reflectance ≧ 45%). Improved photostability in this modified cyanine dye is explained by a two-step photoinduced electron transfer (2-step PET) process between intramolecular Donor (Cyanine)-Acceptor (TCNQ) couple.

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