Resonant photoemission observations and DFT study of s-d hybridization in catalytically active gold clusters on ceria nanorods

Yunyun Zhou; Neil J. Lawrence; Lu Wang; Lingmei Kong; Tai-Sing Wu; Jing Liu; Yi Gao; Joseph R. Brewer; Vivianna K. Lawrence; Renat F. Sabirianov; Yun-Liang Soo; Xiao Cheng Zeng; Peter A. Dowben; Wai Ning Mei; Chin Li Cheung

doi:10.1002/anie.201301383

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Resonant photoemission observations and DFT study of s-d hybridization in catalytically active gold clusters on ceria nanorods

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Resonant photoemission observations and DFT study of s-d hybridization in catalytically active gold clusters on ceria nanorods

Yunyun Zhou, Neil J. Lawrence, Lu Wang, Lingmei Kong, Tai-Sing Wu, Jing Liu, Yi Gao, Joseph R. Brewer, Vivianna K. Lawrence, Renat F. Sabirianov, …

Angewandte Chemie - International Edition, Vol.52(27), pp.6936-6939

01/07/2013

DOI: https://doi.org/10.1002/anie.201301383

Abstract

cerium oxide

gold catalysts

hybridization

resonant photoemission spectroscopy

Up shift: 6s-5d hybridization and the up-shift of the 5d band to the Fermi level is demonstrated in catalytically active gold clusters on a cerium oxide nanorod support by using resonant photoemission spectroscopy and density functional theory modeling. These results help to explain the high catalytic activity of this system in CO oxidation. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Title: Resonant photoemission observations and DFT study of s-d hybridization in catalytically active gold clusters on ceria nanorods
Creators - without role: Yunyun Zhou - University of Nebraska–Lincoln
Neil J. Lawrence - University of Nebraska–Lincoln
Lu Wang - University of Nebraska at Omaha
Lingmei Kong - University of Nebraska–Lincoln
Tai-Sing Wu - Department of Physics , National Tsing Hua University , National Synchrotron Radiation Research Center
Jing Liu - University of Nebraska–Lincoln
Yi Gao - University of Nebraska–Lincoln
Joseph R. Brewer - University of Nebraska–Lincoln
Vivianna K. Lawrence - University of Nebraska–Lincoln
Renat F. Sabirianov - University of Nebraska at Omaha
Yun-Liang Soo - National Tsing Hua University
Xiao Cheng Zeng - University of Nebraska–Lincoln
Peter A. Dowben - University of Nebraska–Lincoln
Wai Ning Mei - University of Nebraska at Omaha
Chin Li Cheung - University of Nebraska–Lincoln
Publication Details: Angewandte Chemie - International Edition, Vol.52(27), pp.6936-6939
Identifiers: 9957768096306774
Academic Unit: Science and Technology of Synchrotron Light Source Program, College of Science, National Tsing Hua University
Language: English
Resource Type: Journal article

Resonant photoemission observations and DFT study of s-d hybridization in catalytically active gold clusters on ceria nanorods

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