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Rhodium(III)-catalyzed ortho-arylation of anilides with aryl halides
Journal article   Peer reviewed

Rhodium(III)-catalyzed ortho-arylation of anilides with aryl halides

Radhakrishnan Haridharan, Krishnamoorthy Muralirajan and Chien-Hong Cheng
Advanced Synthesis and Catalysis, Vol.357(2-3), pp.366-370
09/02/2015
DOI: https://doi.org/10.1002/adsc.201400798

Abstract

C-c coupling C-h activation Homogeneous catalysis Iodobenzene N -phenylpivalamide Rhodium
c 2015 Wiley-VCH Verlag GmbH&Co. KGaA, Weinheim.An efficient o-arylation of pivalamides by aryl iodides via rhodium(III)-catalyzed C-H activation is demonstrated for the first time. Further, the biaryl products can be converted effectively into biologically active phenanthridine and phenanthridinone derivative.

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