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Room temperature photo-induced phase transitions of VO2 nanodevices
Journal article   Peer reviewed

Room temperature photo-induced phase transitions of VO2 nanodevices

Jyh Ming Wu and Lian Bang Liou
Journal of Materials Chemistry, Vol.21(14), pp.5499-5504
14/04/2011

Abstract

We have successfully fabricated VO 2 nanodevices using a photo-induced phase transition mechanism under an ultraviolet-light (λ = 365 nm, I = 7 μW cm -2 ). On the obtained VO 2 nanowires, the photo-induced insulator-to-metal (IM) phase transition occurred from monoclinic (insulator or semiconductor) to tetragonal (metal) structures at room temperature. The photocurrent-to-dark current ratio of the nanodevice was 285 with ultra-fast response and recovery times of 1.3 and 4.5 ms, respectively, at a UV light intensity of 7 μW cm -2 . As the UV light intensity increased to 2.33 mW cm -2 , a maximum photocurrent-to-dark current ratio of 719 was observed. A high-resolution transmission electron microscopy (HRTEM) image indicates that the nanowires grew along the [100] axis as a single crystal. The VO 2 nanowires were then fabricated into field-effect transistor (FET) devices. High electron mobilities of 29 and 7.93 cm 2 V -1 S -1 were obtained with UV on (2.33 mW cm -2 ) and off, respectively. The electrical properties of the photo-induced IM phase transitions of the VO 2 nanowires were investigated. © 2011 The Royal Society of Chemistry.

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