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Selective area growth of high-density GaN nanowire arrays on Si(111) using thin AlN seeding layers
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Selective area growth of high-density GaN nanowire arrays on Si(111) using thin AlN seeding layers

C.H. Wu, P.Y. Lee, K.Y. Chen, Y.T. Tseng, Y.L. WangK.Y. Cheng
Journal of Crystal Growth, 卷.454, 頁碼.71-81
11/2016

摘要

AlN GaN Nanowires Photoluminescence Selective area growth Condensed Matter Physics Inorganic Chemistry Materials Chemistry
Selective area growth (SAG) of high-density (2.5×10 9  cm −2 ) GaN nanowires (NWs) on Si(111) substrate by plasma-assisted molecular beam epitaxy is presented. The effects of morphology and thickness of the AlN seeding layer on the quality of SAG GaN NWs are investigated. A thin AlN seeding layer of 30 nm thick with a surface roughness of less than 0.5 nm is suitable for high quality SAG GaN NWs growth. High-density AlN nanopedestal arrays used as seeds for SAG GaN NWs are fabricated from thin AlN seeding layers using soft nanoimprint lithography. By adjusting the growth temperature and Ga/N flux ratio, hexagonal shaped SAG GaN NWs are realized. The quality of SAG GaN NWs is evaluated by low temperature photoluminescence (PL) measurements. Three major groups of PL peaks at 3.47, 3.45, and 3.41 eV are identified. The peak at 3.471 eV is related to the neutral donor-bound exciton emission, and the 3.41 eV broadband emission is attributed to stacking faults or structural defects. The 3.45 eV peak is identified as the emission due to exciton recombination at polar inversion domain boundaries of NWs.

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