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Selective deposition of films of polypyrrole, polyaniline and nickel on hydrophobic/hydrophilic patterned surfaces and applications
Journal article   Peer reviewed

Selective deposition of films of polypyrrole, polyaniline and nickel on hydrophobic/hydrophilic patterned surfaces and applications

Z. Huang, P.-C. Wang, J. Feng, A.G. MacDiarmid, Y. Xia and G.M. Whitesides
Synthetic Metals, Vol.85(1-3), pp.1375-1376
15/03/1997

Abstract

Polyaniline and derivatives Polypyrrole and derivatives Scanning electron microscopy UV-Vis-NIR absorption
Computer-generated patterned hydrophobia films are produced on hydrophilic glass substrates by a microcontact "stamp" printing technique. The hydrophobic pattern is produced when the silicone elastomeric stamp ("inked" with C 18 H 37 SiCl 3 ) contacts the hydrophilic surface. Thin films of polypyrrole and polyaniline are deposited preferentially on the hydrophobic patterned surfaces from dilute aqueous solutions of the polymerizing monomer. Conversely, strongly adhering films of metals such as nickel are deposited selectively by an electroless process on the hydrophilic substrate surfaces. The properties of the polymers deposited on the hydrophilic and hydrophobic surfaces will be discussed as well as the application of the patterned polymer in liquid crystal displays.

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