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Self-assembly and ring-opening metathesis polymerization of cyclic conjugated molecules on highly ordered pyrolytic graphite
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Self-assembly and ring-opening metathesis polymerization of cyclic conjugated molecules on highly ordered pyrolytic graphite

Shih-Ting Chiu, Hsin-Yu Chiang, Yen-Jen Lin, Yun-Yung Lu, Hirofumi Tanaka, Takuya HosokaiMasaki Horie
Chemical Communications, 卷.54(44), 頁碼.5546-5549
2018

摘要

Catalysis Electronic Optical and Magnetic Materials Ceramics and Composites Chemistry (all) Surfaces Coatings and Films Metals and Alloys Materials Chemistry
Cyclic conjugated monomers comprising cyclopentadithiophene-vinylene trimers and their polymers on HOPG are observed using STM and AFM. ROMP of the monomers is performed using a Grubbs catalyst. Their STM images exhibit single chains of planar polymers, whereas their AFM images show elongation of the polymer chains on HOPG.

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